Journal of Organometallic Chemistry p. 147 - 160 (1988)
Update date:2022-08-10
Topics:
Bacque, E.
Pillot, J.-P.
Birot, M.
Dunogues, J.
Bourgeois, G.
A method for synthesizing novel linear polysilmethylenes of general formula Me(HMeSiCH2)xSiMe2H (VIIx) is described.This strategy involves the cocondensation of chloromethylsilanes HMe2Si(CH2SiMeH)mCH2Cl (m=0 or 1) with methyldichlorosilane and 1,3-dichloro-1,3-dimethyl-1,3-disilapropane, respectively, by Grignard reactions.Thus, short chain polycarbosilanes possessing terminal dimethylhydrogensilyl groups were prepared (2
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(1987)
