Journal of Organometallic Chemistry p. 393 - 400 (1981)
Update date:2022-08-11
Topics:
Veber, M.
Duong, K.N.-V.
Gaudemer, A.
Johnson, M. D.
Allyl(pyridine)cobaloximes RCo(dmgH)2Py (R = allyl) react readily with diethyldibromomalonate, diethylbromomethylmalonate and ethyl 2-bromoacetoacetate to give the corresponding allyl-substituted esters.Transfer of the allyl group occurs with complete rearrangement in all but one cases.Buten-3-yl(pyridine)cobaloximes react with diethylbromomalonate giving cyclopropylmethylmalonic esters.
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