
Journal of Fluorine Chemistry p. 7 - 8 (1995)
Update date:2022-08-16
Topics:
Zupan, Marko
Iskra, Jernej
Stavber, Stojan
The type of functionalization of an aromatic molecule achieved with 1-chloro-4-fluoro-1,4-diazobicyclo-(2,2,2)octane bis-tetrafluoroborate, 'F-TEDA-BF4', in trifluoroacetic acid depends on its structure: naphthalene and phenanthrene gave fluorinated products, anthracene gave the trifluoroacetate, while an addition process occurred with 9-methoxy-phenanthrene in methanol, and an addition-elimination process in trifluoroacetic acid. - Keywords: Solvent effects; Fluorination; Aromate molecules; F-TEDA-BF4; Structural effects; Addition processes
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