Stereochemistry of the enolate from methyl phenylacetate

DOI: 10.1016/S0040-4039(00)74769-1

Source and publish data:

Tetrahedron Letters p. 7885 - 7888 (1992)

Update date:2022-08-30

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Authors:

Tanaka Tanaka

Fuji Fuji

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Article abstract of DOI:10.1016/S0040-4039(00)74769-1

Deprotonation of methyl phenylacetate with lithium diisopropylamide in tetrahydrofuran followed by trapping with trimethylsilyl chloride afforded an 81:19 mixture of E- and Z-silyl ketene acetals in agreement with a prediction by the calculation by Dauben

Full text of DOI:10.1016/S0040-4039(00)74769-1

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