Syntheses of 2-t-Alkylbuta-1,3-dienes and 2-Alkylthiobuta-1,3-dienes from 1,4-Dichlorobut-2-yne via Alkenylboranes

DOI: 10.1039/c39870001629

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1629 - 1631 (1987)

Update date:2022-08-16

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Authors:

Hoshi, Masayuki

Masuda, Yuzuru

Arase, Akira

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Article abstract of DOI:10.1039/c39870001629

2-t-Alkylbut-1,3-dienes were synthesized by the successive reaction of dialkylboranes, derived from tetrasubstituted ethenes and borane in tetrahydrofuran, with 1,4-dichlorobut-2-yne and methyl-lithium; 2-alkylthiobuta-1,3-dienes were synthesized by a sim

Full text of DOI:10.1039/c39870001629

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