On the mechanism of the ruthenium-catalyzed reconstitutive condensation of allylic alcohols and terminal alkynes

DOI: 10.1021/ja00040a015

Source and publish data:

Journal of the American Chemical Society p. 5579 - 5584 (1992)

Update date:2022-08-10

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Authors:

Trost, Barry M.

Kulawiec, Robert J.

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Article abstract of DOI:10.1021/ja00040a015

The ruthenium complex (η⁵C₅H₅)(PPh₃)₂RuCl (1) catalyzes the addition of allylic alcohols to terminal alkynes, yielding β,γ-unsaturated ketones. The intermediacy of a ruthenium vinylidene complex is in

Full text of DOI:10.1021/ja00040a015

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