The Kinatics of the Reaction of with Various Olefins

DOI: 10.1039/DT9940000951

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 951 - 954 (1994)

Update date:2022-08-25

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Authors:

Alibrandi, Giuseppe

Mann, Brian E.

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Article abstract of DOI:10.1039/DT9940000951

A detailed kinetic investigation of the reaction of with cycloheptatriene, cyclohepta-1,3-diene, cyclooctatetraene, penta-1,4-diene, cycloocta-1,5-diene and dimethyl maleate, has been carried out spectrophotometrically in CH2Cl2 at 10 deg C.It is shown that the major mechanism is via dissociation of PPh3 to give which then reacts with the olefin.There is also a second mechanism involving direct attack of the olefin on .

Full text of DOI:10.1039/DT9940000951

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