Unsymmetrical functionalization of 1,3-cyclohexadienes: Palladium- catalyzed stereoselective 1,4-acyloxy-alkoxylation

DOI: 10.1016/S0040-4020(98)00212-9

Source and publish data:

Tetrahedron p. 5375 - 5384 (1998)

Update date:2022-08-25

Topics:

Authors:

Hupe, Eike

Itami, Kenichiro

Aranyos, Attila

Szabo, Kalman J.

Baeckvall, Jan-E

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Article abstract of DOI:10.1016/S0040-4020(98)00212-9

Palladium-catalyzed reaction of 1,3-cyclohexadiene with alcohols and acetic or benzoic acid under mild acidic conditions gives trans-1-acetoxy- or trans-1-benzyloxy-4-alkoxy-2-cyclohexenes, respectively, with high regio- and stereo-selectivity. The unsymm

Full text of DOI:10.1016/S0040-4020(98)00212-9

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