Tetrahedron Letters p. 7961 - 7964 (1999)
Update date:2022-08-30
Topics:
Leste-Lasserre, Pierre
Harpp, David N.
The chemistry of one of the sulfur allotropes has been investigated. Cyclodecasulfur (S10) reacts with conjugated 1,3-dienes and strained olefins to deliver cyclic di- and polysulfides with a better selectivity and under milder conditions than with elemental sulfur (S8). A radical mechanism is proposed for these sulfuration reactions.
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