A short and selective synthesis of (S)-geranylcitronellol via conjugate addition of a functionalized copper reagent to 2-substituted exo-bornyl crotonates

DOI: 10.1016/0040-4039(96)01557-2

Source and publish data:

Tetrahedron Letters p. 7127 - 7128 (1996)

Update date:2022-08-28

Topics:

Authors:

Johansson, Anders

Olsson, Thomas

Bergstroem, Gunnar

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Article abstract of DOI:10.1016/0040-4039(96)01557-2

An asymmetric synthesis of the diterpene (S)-geranylcitronellol 1a and its acetate 1b is reported. The chirality is induced by TMSI-promoted conjugate addition of a homoallylic monoorganocopper reagent to 2-naphthyl-exo-bornylcrotonate, which proceeds wit

Full text of DOI:10.1016/0040-4039(96)01557-2

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