Bis, N-Chlorobis(F-methyl)sulfimide, and N-Fluorobis(F-methyl)sulfimide

Article abstract of DOI:10.1021/ja00398a012

The first member of a new class of stable sulfimides, bis, (CF3)2S=NN=S(CF3)2, results from the photolysis of (CF3)2S=NCl.The latter is prepared by reacting (CF3)2S=NH with ClF in the presence of CsF.Under similar conditions, (CF3)2S=NH reacts with SF4 to give (CF3)2S=NF.