Preparation and Chiroptical Properties of Optically Active Vinyl Ether-Iron and Olefin-Iron Complexes. A CD Quadrant Rule Correlating Absolute Configurations.

DOI: 10.1021/ja00196a036

Source and publish data:

Journal of the American Chemical Society p. 5252 - 5259 (1989)

Update date:2022-08-11

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Authors:

Begum, M. Kohinoor

Chu, Kai-Hsuan

Coolbaugh, Thomas S.

Rosenblum, Myron

Zhu, Xiao-Ya

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Article abstract of DOI:10.1021/ja00196a036

Exchange etherification of dicarbonylcyclopentadienyl(η²-ethyl vinyl ether)iron tetrafluoroborate (4) with optically active primary and secondary alcohols yields a mixture of diastereomeric cations.These isomers are in rapid equilibrium at room

Full text of DOI:10.1021/ja00196a036

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