Spectroscopic Characterization of Triplet 4,5-Benzocycloheptatrienylidene

DOI: 10.1021/ja00210a038

Source and publish data:

Journal of the American Chemical Society p. 539 - 545 (1988)

Update date:2022-08-17

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Authors:

Chateauneuf, John E.

Horn, Keith A.

Savino, Thomas G.

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Article abstract of DOI:10.1021/ja00210a038

4,5-Benzodiazocycloheptatriene (6) has been prepared by the low temperature nickel peroxide oxidation of the hydrazone of 4,5-benzotropone.Thermolysis of 6 in benzene produces 4,5-benzocycloheptatrienylidene (1) which undergoes a facile carbene-carbene re

Full text of DOI:10.1021/ja00210a038

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