Tetrahedron Letters p. 4271 - 4274 (1991)
Update date:2022-08-11
Topics:
Morken, Peter A.
Lu, Hengyao
Nakamura, Akihiro
Burton, Donald J.
The title compounds are prepared by metallation of CF3CH=CF2 with LDA or t-BuLi or by metallation of CF3CBr2CF3 with 2 equivalents of zinc.CF3C(ZnX)=CF2 undergoes halogenation, oxidative dimerization, allylation and acylation reactions. Key Words: vinyl organofluorine zinc reagent; organolithium; zinc; oxidative coupling; halogenation
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