Journal of the Chemical Society. Chemical communications p. 1379 - 1381 (1984)
Update date:2022-08-31
Topics:
Hamilton, James G.
Ivin, Kenneth J.
McCann, G. Malachy
Rooney, John J.
A detailed study of the microstructures of ring-opened polymers of norbornene and several methyl derivatives, using salts of Ru and Os as catalysts, shows that the widely noted stereoselective feature of cis giving cis and trans giving trans in olefin metathesis is attributable to different forms of metallacarbene propagating species rather than to different configurations of putative metallacyclobutanes derivable from the same metallacarbene.
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