Tetrahedron Letters p. 5181 - 5184 (1998)
Update date:2022-08-12
Topics:
Cabanal-Duvillard, Isabelle
Berrien, Jean-Francois
Royer, Jacques
Husson, Henri-Philippe
Bromination and bromohydroxylation of oxazolidinones derived from cyclohexadiene have been studied in order to synthetize (±)-epibatidine 18. Bromohydroxylation of compound 2 led to a polyfunctionalized halohydrin 11a which could be further cyclized to azabicyclo[2.2.1]heptan-2-one 16 already described as a precursor of epibatidine 18.
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