Journal of Physical Chemistry p. 3689 - 3694 (1990)
Update date:2022-08-31
Topics:
Hiraoka, Kenzo
Mizuse, Susumu
Yamabe, Shinichi
The equilibria of clustering reactions C6F6+/- + C6F6 = C6F6+/-(C6F6) were studied with a pulsed electron beam high-pressure mass spectrometer.Thermochemical stabilities of the clusters C6F6-(C6F6) and C6F6+(C6F6) were determined.It was found that the bond energy of C6F6-(C6F6) is larger than that of C6F6+(C6F6).While C6F6+(C6F6) has the site-to-site type geometry, C6F6-(C6F6) has a stack form according to the ab initio MO calculation.
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