STEREOSELECTIVE REDUCTION OF α-HYDROXY KETONES

DOI: 10.1016/S0040-4039(00)87969-1

Source and publish data:

Tetrahedron Letters p. 2653 - 2656 (1983)

Update date:2022-08-11

Topics:

Authors:

Nakata, Tadashi

Tanaka, Tadasu

Oishi, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)87969-1

Reduction of α-hydroxy ketones with zinc borohydride afforded the erythro-glycols in high stereoselectivity, while reduction of their α-(t-butyldiphenylsilyl)oxy derivatives with sodium bis(2-methoxyethoxy)aluminum hydride gave the isomeric threo-glycols.

Full text of DOI:10.1016/S0040-4039(00)87969-1

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