STEREOSELECTIVE REDUCTION OF α-HYDROXY KETONES

DOI: 10.1016/S0040-4039(00)87969-1

Source and publish data:

Tetrahedron Letters p. 2653 - 2656 (1983)

Update date:2022-08-11

Topics:

Authors:

Nakata, Tadashi

Tanaka, Tadasu

Oishi, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87969-1

Reduction of α-hydroxy ketones with zinc borohydride afforded the erythro-glycols in high stereoselectivity, while reduction of their α-(t-butyldiphenylsilyl)oxy derivatives with sodium bis(2-methoxyethoxy)aluminum hydride gave the isomeric threo-glycols.

Full text of DOI:10.1016/S0040-4039(00)87969-1

Products guided by the article

Product name:erythro-1-Phenylpropane-1,2-diol

Cas No:40421-52-1

R&D Labs maybe for 40421-52-1

Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
Beijing eternalchem Co,. Ltd

Contact:+86-10-59484199

Address:No.58-A1026 Liangguan Street

Relevant to this article

Mechanistic investigation of the reaction of epoxides with heterocumulenes catalysed by a bimetallic aluminium salen complex

Doi:10.1002/chem.201400007
(2014)
An Efficient and General Method for Formylation of Aryl Bromides with CO₂ and Poly(methylhydrosiloxane)

Doi:10.1002/chem.201504320
(2016)
Synthesis, spectral, thermal and biological studies of Co(III) and binuclear Ni(II) complexes with a novel amine-imine-oxime ligand

Doi:10.1134/S1070363208090260
(2008)
Synthesis of (±)-gymnomitrol. Mn(OAc)₃-initiated free-radical cyclization of alkynyl ketones

Doi:10.1021/jo9622338
(1997)
The synthesis of di-carboxylate esters using continuous flow vortex fluidics

Doi:10.1039/c5gc02494c
(2016)
FeCl3-catalyzed Pechmann synthesis of coumarins in ionic liquids

Doi:10.1080/00397910802219569
(2008)

Article Doi