Unexpected Generation and Rearrangement of Acetyl Benzotriazolyl Carbene

DOI: 10.1039/c39930001517

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1517 - 1519 (1993)

Update date:2022-08-11

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Authors:

Aitken, R. Alan

Fairhurst, Ian M.

Ford, Adrian

Milne, Paul E. Y.

Russell, Duncan W.

Whittaker, Martin

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Article abstract of DOI:10.1039/c39930001517

Flash vacuum pyrolysis of one example from a wide range of α-benzotriazolyl-β-oxo phosphorus ylides results in extrusion of Buⁿ3P to give 3-acetyl-1,2,4-benzotriazine and o-cyanoacetophenone, products apparently derived from rearrangement of th

Full text of DOI:10.1039/c39930001517

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