Carbonylation of Selenilimines to Arylsulfonyl Isocyanates

DOI: 10.1016/0040-4039(94)88523-0

Source and publish data:

Tetrahedron Letters p. 9609 - 9610 (1994)

Update date:2022-08-29

Topics:

Authors:

Besenyei, Gabor

Nemeth, Sandor

Simandi, Laszlo I.

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Article abstract of DOI:10.1016/0040-4039(94)88523-0

Selenilimines of general formula ArSO2N=SePh2, 1, can be catalytically carbonylated to arylsulfonyl isocyanates, 2, in the presence of palladium complexes as catalysts.This transformation represents a new two-step oxidative N-carbonylation reaction.

Full text of DOI:10.1016/0040-4039(94)88523-0

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