Tetrahedron Letters p. 9609 - 9610 (1994)
Update date:2022-08-29
Topics:
Besenyei, Gabor
Nemeth, Sandor
Simandi, Laszlo I.
Selenilimines of general formula ArSO2N=SePh2, 1, can be catalytically carbonylated to arylsulfonyl isocyanates, 2, in the presence of palladium complexes as catalysts.This transformation represents a new two-step oxidative N-carbonylation reaction.
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