Journal of the Chemical Society. Chemical communications p. 1329 - 1331 (1985)
Update date:2022-08-11
Topics:
Cullis, Paul M.
Kay, Paul B.
Trippett, Stuart
The title compounds together give pyrophosphate and methyl chloride probably via a cycle of reactions involving cyclic phosphate diester and hydrogen chloride as carriers; rapid formation of dioxadiphosphetanes from intermediate five-co-ordinate phosphoranes and a slower intermolecular scrambling account for the distributions of 18O observed starting with various patterns of 18O labelling.
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