Synthesis p. 1830 - 1834 (2004)
Update date:2022-08-11
Topics:
Wakharkar, Radhika D.
Sahasrabuddhe, Manjusha B.
Borate, Hanumant B.
Gurjar, Mukund K.
Alkyl 2,3-O-isopropylidene-5-O-methoxymethylfuranoside derivatives undergo selective cleavage of the 2,3-O-isopropylidene group, if oriented cis to the O-glycoside, in the presence of trifluoroacetic acid. Otherwise, the cleavage of the 5-O-methoxymethyl group is favoured over the 2,3-O-isopropylidene group.
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(2015)