Journal of the Chemical Society. Chemical communications p. 132 - 134 (1992)
Update date:2022-08-16
Topics:
Dessolin, Michele
Eisenstein, Odile
Golfier, Michel
Prange, Thierry
Sautet, Philippe
Using 5-methoxy-2-aryl-1,3,4-oxadiazoles as models it was shown that the thermal rearrangement of imino-ethers to N-alkylamides proceeds through a double ionic mechanism; kinetics measurements in the solid state and in the melt give apparent activation energies that support ab initio calculated activation enthalpies.
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