Journal of the Chemical Society. Chemical communications p. 395 - 396 (1983)
Update date:2022-08-11
Topics:
Hasegawa, Tadashi
Arata, Yoshiaki
Mizuno, Kouichi
The excited ketone carbonyl group in the α-alkyl β-oxoamide (1a-e) abstracts γ- and δ-hydrogen competitively from the n,?* triplet state; the δ-hydrogen abstraction greatly predominates over the γ-hydrogen abstraction in the photolyses of (1c) and (1d).
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