Electroorganic Reactions on Organic Electrodes. 6. Electrochemical Asymmetric Oxidation of Unsymmetric Sulfides to the Corresponding Chiral Sulfoxides on Poly(amino acid)-Coated Electrodes

DOI: 10.1021/ja00321a028

Source and publish data:

Journal of the American Chemical Society p. 2656 - 2659 (1984)

Update date:2022-08-28

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Authors:

Komori, Tetsuo

Nonaka, Tsutomu

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Article abstract of DOI:10.1021/ja00321a028

Alkyl aryl sulfides (1a-g) were electrochemically oxidized to the corresponding chiral sulfoxides (2a-g) (eq 1) by using poly(amino acid)-coated electrodes.The highest optical yield was 93percent, which was obtained in the oxidation of tert-butyl phenyl s

Full text of DOI:10.1021/ja00321a028

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