C3 EPIMERIZATION AND SELECTIVE C2-C3 BOND FISSION OF ALKYL CHRYSANTHEMATE

DOI: 10.1016/S0040-4039(01)90020-6

Source and publish data:

Tetrahedron Letters p. 1595 - 1598 (1984)

Update date:2022-08-11

Topics:

Authors:

Suzukamo, Gohfu

Fukao, Masami

Tamura, Mitsuhisa

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Article abstract of DOI:10.1016/S0040-4039(01)90020-6

Treatment of alkyl chrysanthemate with Lewis acid leads to C₃ epimerization, while protonic acid treatment gives rise to selective C₂-C₃ bond cleavage.The latter method is succesfully applied to the synthesis of optically active tetrahydrolavandulol.

Full text of DOI:10.1016/S0040-4039(01)90020-6

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