Journal of the American Oil Chemists' Society p. 1021 - 1026 (1995)
Update date:2022-08-11
Topics:
Knothe, G.
Bagby, M. O.
Weisleder, D.
Several symmetrical alkenes were reacted with the selenium dioxide/tert.-butylhydroperoxide system to give three hydroxylated products each.These products were those of allylic mono- and dihydroxylation (meso and threo dihydroxy compounds) of the double bond.Some dihydroxy products were hydrogenated to give saturated 1,4-diols.The compounds were characterized by nuclear magnetic resonance.The products have potential for application in commercial products, such as biodiesel, lubricants, greases, and cosmetics. - Keywords: Hydroxylation; nuclear magnetic resonance; selenium dioxide; symmetrical alkene, tert.-butylhydroperoxide.
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