Tetrahedron Letters p. 1465 - 1468 (1985)
Update date:2022-08-17
Topics:
Evans, Stephen V.
Hayman, Alison R.
Fellows, Linda E.
Shing, Tony K. M.
Derome, Andrew E.
Fleet, George W. J.
A COSY spectrum has been used to determine the position of inter-residue linkage in 4-O-(β-D-glucopyranosyl) fagomine (1) an example of a new class of glycosides of polyhydroxylated piperidine alkaloids isolated from seed of the legume Xanthocercis zambesiaca. (Bak.) Dunn.Unlike a number of polyhydroxylated piperidines, neither the glucoside (1) nor the fagomine <1,2,5-trideoxy-1,5-imino-D-arabitohexitol> (3) showed any inhibitory activity towards glycosidase enzymes from a variety of sources.
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