Journal of the Chemical Society. Perkin transactions I p. 763 - 768 (1988)
Update date:2022-08-11
Topics:
Demetriadou, Agathi K.
Laue, Ernest D.
Leeper, Finian J.
Staunton, James
The isolation and characterization of polivione, a polyketide metabolite and probably a precursor of citromycetin (1), from Penicillium frequentans is reported.The structure elucidation of polivione is based on a detailed study of its high-field (1)H and (13)C n.m.r. spectra.Extensive use was made of two-dimensional homonuclear and heteronuclear correlation experiments in the assignment of the n.m.r. spectra.Some chemical transformations were also explored, both to confirm its structure and to investigate its relationship to citromycetin.
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