Chemistry Letters p. 1411 - 1414 (1980)
Update date:2022-08-17
Topics:
Ito, Sotaro
Yamamoto, Toshimasa
Tokushige, Yuji
The copper(II) chloride-catalyzed oxidation of L-ascorbic acid (AA) by O2 was found to involve both the anaerobic oxidation of AA by copper(II) chloride and the reoxidation steps of copper(I) chloride by O2 in the catalytic cycle, by comparing the rate of copper(II)-catalyzed oxidation of AA by O2 (RAIIO) with those of anaerobic oxidation of AA by copper(II) (RAII) and oxidation of copper(I) by O2 (RIO).
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