Journal of the Chemical Society. Chemical communications p. 1487 - 1489 (1991)
Update date:2022-08-10
Topics:
Maldotti, A.
Bartocci, C.
Amadelli, R.
Polo, E.
Battioni, P.
Mansuy, D.
Cycloalkanes were oxidized by O2 itself under mild conditions (22 deg C; 200 Torr of O2) in the presence of catalytic amounts of a polyhalogenated porphyrin-iron(III)-hydroxo complex irradiated with light of wavelength between 350 and 450 nm; these oxidations occurred without consumption of a reducing agent, selectively transformed cyclohexane into cyclohexanone under appropriate conditions (about 0.2 turnover per min), and did not involve FeV=O active species but, more probably, iron-alkylperoxo intermediates.
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Doi:10.1007/s11426-011-4378-8
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(1991)
