Chemistry - A European Journal
10.1002/chem.201904731
FULL PAPER
Procedures for tandem dehydrogenation ammonia borane and
hydrogenation of Nitroarenes. Pd@H-PPA (20 mg), nitroarene (0.6
mmol) and methanol (4 mL) and water (5 mL) were placed in a two-necked
round-bottomed flask. After 1.0 mL aqueous solution of AB (31 mg, 1
mmol) was added to the flask, the catalytic reaction started. After a given
time, the reaction was analysed with GC-MS to determine the conversion
and selectivity. For the recyclability tests, after the first run reduction of
nitrobenzene, the same amount of fresh AB (1 mmol) and nitrobenzene
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(
0.6 mmol) was subsequently added. Pd content in Pd@H-PPA was 0.961
[
-
1
mmol g , as determined by ICP.
Procedures for tandem dehydrogenation ammonia borane and
hydrogenation of Nitroarenes in integrated reactor. The tandem
reactions were performed in a three-chamber reactor. Pd@H-PPA (20 mg),
methanol (4 mL) and water (5 mL) were placed in the middle chamber.
Pd@H-PPA (20 mg) with nitrobenzene (0.1 mmol) in ethanol (10 mL) and
p-nitrotoluene (0.1 mmol) in ethanol (10 mL) were separately added into
the left and right chambers. After injection of 1 mL aqueous solution of AB
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(31 mg) into the middle chamber, the hydrogenation of nitroarenes with the
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2
selectivity of product were analyzed with GC-MS.
Acknowledgements
We thank the National Natural Science Foundation of China (No.
82, 1253-1265; f) D. Chakraborty, S. Nandi, D. Mullangi, S.
5
1672046, 51672047 and 21403238), Natural Science
Foundation of Fujian Province of China (No. 2019J01226,
019J01648), Open Project Program of the State Key Laboratory
Haldar, C. P. Vinod, R. Vaidhyanathan, ACS Appl. Mat.
Interfaces 2019, 11, 15670-15679.
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of Photocatalysis on Energy and Environment (No. SKLPEE-
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801233; d) W. Zhong, R. Sa, L. Li, Y. He, L. Li, J. Bi, Z.
Keywords: metal nanoparticles • catalysis • covalent organic
frameworks • hollow sphere • polyamine
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