Tetrahedron Letters p. 4319 - 4322 (1983)
Update date:2022-08-30
Topics:
Cuvigny, T.
Fabre, J. L.
Herve, du Penhoat C.
Julia, M.
The stereospecific reduction of 2-phenylsulfonyl-1,3-dienes 1i to conjugated EZ dienes 2 catalysed by transition metal complexes in the presence of n-butylmagnesium chloride is described.This method is illustrated by the synthesis of the pheromone of Spodoptera littoralis : 9Z,11E-tetradecadien-1-yl acetate 8, R = Ac.
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Doi:10.1002/jps.2600690114
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