CARBONYLATION OF 2 AND 2; A NEW SELECTIVE METHOD FOR PREPARATION OF

DOI: 10.1016/S0022-328X(00)98510-3

Source and publish data:

Journal of Organometallic Chemistry p. 241 - 244 (1983)

Update date:2022-08-31

Topics:

Authors:

Monica, G. La

Monti, C.

Pizzotti, M.

Cenini, S.

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Article abstract of DOI:10.1016/S0022-328X(00)98510-3

Carbonylation of 2 (COD=1,5-cyclooctadiene) in ethanol gave the rhodium cluster selectively in high yield; when non polar solvents were used, the known 2 and 2 were obtained.Reaction of carbon monoxide with the isocyanato-bridged derivative 2 in ethanol also gave .In both cases the carbonylation reaction also gave NH2COOEt.Carbonylation of the iridium dichloride dimer 2 in the presence of sodium citrate gave .

Full text of DOI:10.1016/S0022-328X(00)98510-3

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