Hydrophobic Vitamin B12. I. Preparation and Axial Ligation Behavior of Hydrophobic Vitamin B12r

DOI: 10.1246/bcsj.56.3642

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3642 - 3646 (1983)

Update date:2022-08-02

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Authors:

Murakami, Yukito

Hisaeda, Yoshio

Kajihara, Akiro

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Article abstract of DOI:10.1246/bcsj.56.3642

Heptamethyl cobyrinate perchlorate, ClO4, was prepared in good yield from cyanocobalamin.This hydrophobic complex is structurally comparable to the base-off form of vitamin B_12r.Thermodynamic parameters (ΔG, ΔH, and ΔS) for axial

Full text of DOI:10.1246/bcsj.56.3642

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