Chemistry of Heterocyclic Compounds p. 714 - 718 (1980)
Update date:2022-08-11
Topics:
Leichenko, A. A.
Schedrinskaya, T. V.
Volkov, M. N.
The oxidation of 2-methoxymethylthiophene with molecular oxygen in the presence of a cobalt bromide catalyst in the kinetic region at 65-100 deg C was investigated.It is shown that the principal products are 2-formylthiophene and methylthiophene-2-carboxylate in a ratio of 1:2.The composition of the products does not depend on the oxidation temperature and changes as the starting concentration of 2-methoxymethylthiophene and the amount of cobalt bromide catalyst are changed.
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