The Mechanism of Escherichia coli Dethiobiotin Synthetase-the Closure of the ureido Ring of Dethiobiotin involves Formation of a Carbamic-phosphate Mixed Anhydride

DOI: 10.1039/c39940000759

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 759 - 760 (1994)

Update date:2022-08-11

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Authors:

Baxter, Robert L.

Baxter, Helen C.

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Article abstract of DOI:10.1039/c39940000759

The final intermediate in the enzymatic synthesis of the ureido ring of D-dethiobiotin 1 from (7R,8S)-7,8-diaminononanoate 2 catalysed by E. coli dethiobiotin sunthetase is the phosphoric acid anhydride 4 of the carbamate 3.

Full text of DOI:10.1039/c39940000759

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