THE GENERATION AND SIGMATROPIC REARRANGEMENT OF A DERIVATIVE OF VINYL-TMM (2,5-DIMETHYL-3-ISOPROPYL-4-ISOPROPYLIDENEHEX-2-EN-1,5-DIYL)

DOI: 10.1016/S0040-4039(00)84448-2

Source and publish data:

Tetrahedron Letters p. 2057 - 2060 (1986)

Update date:2022-08-17

Topics:

Authors:

Bushby, Richard J.

Mann, Stephen

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84448-2

The thermal rearrangement of 2,5-dimethyl-3-isopropyl-4-isopropylidenehex-2-en-1,5-diyl to 4-isopropyl-3-isopropylidene-2,5-dimethylhexa-1,4-diene involves a 1,6-sigmatropic shift of hydrogen which may occur in antarafacial manner.

Full text of DOI:10.1016/S0040-4039(00)84448-2

Products guided by the article

Product name:2,5-dimethyl-4-(propan-2-yl)-3-(propan-2-ylidene)hexa-1,4-diene

Cas No:54580-22-2

R&D Labs maybe for 54580-22-2

Chen jie

Contact:027-87677569

Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
QUZHOU ZIO I/E CO.;LTD

Contact:13357117572

Address:No.149 Shiji dadao Road.
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China

Relevant to this article

Single-Ion Magnetic Behavior in Co^II–Co^III Mixed-Valence Dinuclear and Pseudodinuclear Complexes

Doi:10.1002/ejic.201700046
(2017)
Synthesis of phenyl 1-thioglycopyranosiduronic acids using a sonicated Jones oxidation

Doi:10.1016/S0040-4039(98)00155-5
(1998)
Wagner-Meerwein rearrangements in the gas phase: Anchimeric assistance to acid-induced dissociation of optically active phenylpropanols

Doi:10.1002/(SICI)1521-3765(19990301)5:3<834::AID-CHEM834>3.0.CO;2-G
(1999)
Synthesis, spectral characterization, DNA binding ability and antibacterial screening of copper(II) complexes of symmetrical NOON tetradentate Schiff bases bearing different bridges

Doi:10.1016/j.molstruc.2012.04.017
(2012)
Selective Cu(I) complex with phosphine-peptide (SarGly) conjugate contra breast cancer: Synthesis, spectroscopic characterization and insight into cytotoxic action

Doi:10.1016/j.jinorgbio.2018.06.009
(2018)
No carrier added synthesis of O-(2′-[¹⁸F]fluoroethyl)-l-tyrosine via a novel type of chiral enantiomerically pure precursor, Ni^II complex of a (S)-tyrosine Schiff base

Doi:10.1016/j.bmc.2008.03.040
(2008)

Article Doi