THE GENERATION AND SIGMATROPIC REARRANGEMENT OF A DERIVATIVE OF VINYL-TMM (2,5-DIMETHYL-3-ISOPROPYL-4-ISOPROPYLIDENEHEX-2-EN-1,5-DIYL)

DOI: 10.1016/S0040-4039(00)84448-2

Source and publish data:

Tetrahedron Letters p. 2057 - 2060 (1986)

Update date:2022-08-17

Topics:

Authors:

Bushby, Richard J.

Mann, Stephen

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Article abstract of DOI:10.1016/S0040-4039(00)84448-2

The thermal rearrangement of 2,5-dimethyl-3-isopropyl-4-isopropylidenehex-2-en-1,5-diyl to 4-isopropyl-3-isopropylidene-2,5-dimethylhexa-1,4-diene involves a 1,6-sigmatropic shift of hydrogen which may occur in antarafacial manner.

Full text of DOI:10.1016/S0040-4039(00)84448-2

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