Tetrahedron Letters p. 691 - 694 (1996)
Update date:2022-08-25
Topics:
Ackland, Mark J.
Danks, Timothy N.
Howells, Mark E.
Treatment of (1-azadiene)tricarbonyliron(0) complex 1 with lithiated amines leads to attack at a metal carbonyl and the formation of formamides, whereas complexes 2 and 3 undergo deprotonation of the methyl group at C-2 followed by a rearrangement to form (2-aminohomodiene)tricarbonyliron(0) complexes 8 or 10 in good yield.
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