Direct synthesis of acetals by rhodium catalysed hydroformylation of alkenes in the presence of orthoformate

DOI: 10.1016/0022-328X(95)05594-F

Source and publish data:

Journal of Organometallic Chemistry p. C10 - C13 (1995)

Update date:2022-08-11

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Authors:

Soulantica, K.

Sirol, S.

Koinis, S.

Pneumatikakis, G.

Kalck, Ph.

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Article abstract of DOI:10.1016/0022-328X(95)05594-F

The two catalyst precursors 2 and 2 in the presence of 4 equivalents of P(OPh)3 in triethyl orthoformate as solvent and reactant, permit the low pressure hydroformylation of various alkenes into the corresponding acetals.Apart from a few low-yield by-products resulting from isomerization of the substrates, the carbonylated products obtained directly and exclusively are acetals.Keywords: Hydroformylation; Rhodium; Catalysis; Acetals

Full text of DOI:10.1016/0022-328X(95)05594-F

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