Remarkable Decrease in Overpotential of Oxalate Formation in Electrochemical CO2 Reduction by a Metal-Sulfide Cluster

DOI: 10.1039/c39950001223

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1223 - 1224 (1995)

Update date:2022-08-17

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Authors:

Kushi, Yoshinori

Nagao, Hirotaka

Nishioka, Takanori

Isobe, Kiyoshi

Tanaka, Koji

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Article abstract of DOI:10.1039/c39950001223

Triangular metal-sulfide cluster, <3(μ₃-S)2>2+ and <3(μ₃-S)2>2+, catalyse the electrochemical CO2 reduction to selectively produce oxalate at -1.30 and -0.70 V (vs.Ag/AgCl), respectively, in MeCN.

Full text of DOI:10.1039/c39950001223

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