Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2599 - 2608 (1982)
Update date:2022-08-16
Topics:
Aceves, Juan M.
West, Anthony R.
Cells of the type Au/Li4SiO4/Au and Au/Li2TiO3/Au behave as secondary cells at high temperatures, >/=400 deg C.The cell reactants are created in situ by charging the cells in air at e.g. 1.5 V.Electrochemical decomposition of the solid electrolytes occurs giving, as solid products, Li2CO3 at the negative electrode and Li2SiO3 and TiO2, respectively, at the positive electrode.Under different charging conditions other products may be obtained with the Li2TiO3-containing cell.The products of charging form as a layer on the surfaces of the pellet and the gold electrodes appear to take no part in the reactions.The charged cells have open-circuit voltages in the range 0.4 - 0.5 V at ca. 500 deg C and give discharge currents of e.g. 10 - 100 μA through a 10E4 Ω load resistance for several days.
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