Journal of Organometallic Chemistry p. 23 - 34 (1986)
Update date:2022-08-16
Topics:
Lee, W. L.
Shieh, C. F.
Liu, C. S.
The reactions of difluorosilylene with cyclopentadiene and cycloheptatriene were studied both in the gas phase and by the cocondensation method.Several new organosilicon compounds were synthesized and their structures characterized.In the cycloheptatriene reaction the comparison between the results from the gas phase and cocondensation experiments provides the first solid evidence which makes it possible to differentiate between the silirane mechanism and the .SiF2SiF2. diradical mechanism in the "addition reactions" of difluorosilylene.
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