Journal of the Chemical Society. Chemical communications p. 47 - 49 (1986)
Update date:2022-08-16
Topics:
Sarel, Shalom
Avramovici-Grisaru, Schely
Cohen, Shmuel
Iron(II) ions are shown to induce a hitherto unknown nitrogen-centred metathesis ('hydrazine metathesis')of pyridoxal isonicotinoylhydrazone dimethiodide (1) into the symmetrical hydrazine derivatives pyridoxal azine dimethiodide (7) and dimethiodide of bis-isonicotinoyl hydrazide (8) together with isonicotinoylamide methiodide (9) in a ratio 2:1:1, respectively.
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