Tetrahedron Asymmetry p. 2363 - 2370 (1993)
Update date:2022-08-31
Topics:
Money, Thomas
Palme, Monica H.
Treatment of (-)2-methylenebornane (7), derived from (+)-camphor (1), with 45percent HBr/HOAc results in Wagner-Meerwein rearrangement and formation of 4-methylisobornyl bromide (17) in 80-90percent yield.The enantiopurity of (17) was determined by conversion to (+)-4-methylisoborneol (5) and (-)-4-methylcamphor (3).
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