Tetrahedron Letters p. 2055 - 2058 (1988)
Update date:2022-08-16
Topics:
Zylber, J.
Ouazzani-Chahdi, L.
Chiaroni, A.
Riche, C.
C-5 methylation of the model purine compound caffeine by acetyl benzoyl peroxide is the result of preferential addition of the electrophilic benzoyloxy radical at C-8 in neutral medium.X-ray structure and molecular orbital calculations on 1,3,5,7-tetramethyl-5,7-dihydrouric acid are presented.
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Doi:10.1038/168518b0
(1951)Doi:10.1039/c4ra03362k
(2014)Doi:10.1021/ja01867a068
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(1978)Doi:10.1055/s-0034-1379926
(2015)Doi:10.1002/chem.202002305
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