Exciton Effects in Chiral Planar 1,3-Dienes and α,β-Unsaturated Carbonyl Compounds. Configurational Application

DOI: 10.1021/ja00256a028

Source and publish data:

Journal of the American Chemical Society p. 6726 - 6730 (1987)

Update date:2022-08-17

Topics:

Authors:

Gawronski, J. K.

Reddy, S. Madhava

Walborsky, H. M.

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Article abstract of DOI:10.1021/ja00256a028

A new application of exciton coupling between a benzoate chromophore and planar 1,3-diene as well as α,β-unsaturated carbonyl chromophore (aldehyde, ketone, or ester) for determination of the absolute configuration of axially dissymmetric molecules is reported.The effect of Z/E configuration of the chromophore on exciton interaction is noted.

Full text of DOI:10.1021/ja00256a028

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