Synthesis of Triscyclopentadienyl(triphenylgermyl)uranium and Facile Isonitrile Insertion into the Uranium-Germanium Bond

DOI: 10.1039/c39870000550

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 550 - 551 (1987)

Update date:2022-08-10

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Authors:

Porchia, Marina

Ossola, Franco

Rossetto, Gilberto

Zanella, Pierino

Brianese, Nicola

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Article abstract of DOI:10.1039/c39870000550

The uranium-germanium bonded complex (cp)3UGePh3 (1) (cp = η⁵-C5H5) has been prepared from (cp)3UCl and KGePh3 and fully characterized; it reacts readily with 2,6-dimethylphenyl isocyanide <(Xyl)NC> to give the carbamoyl insertion product (cp)3

Full text of DOI:10.1039/c39870000550

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