Synthesis of (chlorovinyl)cobaloxime complexes, model complexes of proposed intermediates in the B12-catalyzed dehalogenation of chlorinated ethylenes

DOI: 10.1039/b109001a

Source and publish data:

Chemical Communications p. 234 - 235 (2002)

Update date:2022-08-17

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Authors:

Rich, Autumn E.

DeGreeff, Angela D.

McNeill, Kristopher

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Article abstract of DOI:10.1039/b109001a

(Chlorovinyl)cobaloxime complexes, (dmgH)₂(py)CoR (R = cis-dichlorovinyl, trans-2-chlorovinyl or 1-chlorovinyl, dmgH = dimethylglyoximate) were synthesized from the reaction of chlorinated ethylenes with in situ generated (dmgH)₂Co(I) in the presence of pyridine.

Full text of DOI:10.1039/b109001a

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