Journal of Organometallic Chemistry p. C7 - C10 (1988)
Update date:2022-08-16
Topics:
Alt, Helmut G.
Schwind, Karl-Heinz
Rausch, Marvin D.
Thewalt, Ulf
The reaction of Cp2Ti(PMe3)2 (1) and ethylene affords the 16-electron species Cp2TiC2H4 (2).In a reaction of 2 and ethylene under pressure, 1-butene and trans-2-butene are formed catalytically.With water, 2 reacts to give the dinuclear μ-oxo complex (Cp2TiEt)2O (3) the structure of which has been determined by X-ray diffraction.
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